EnergyPlus calculates the inside/outside air film resistances during simulation so you don't need to specify these (see Construction).
If you want to enter the thermal performance yourself you can use the simplified Material:NoMass and/or WindowMaterial:SimpleGlazingSystem objects. However, the EnergyPlus documentation cautions against these because the effects of thermal mass are not considered - i.e. it assumes steady state heat transfer - and the results may differ significantly from the more detailed Material and WindowMaterial:Glazing objects.
Otherwise if you want to know the thermal performance of a Construction assembly pre-simulation you'll need to calculate it from each layer's properties (thickness, conductivity, etc), and then change one or more of these fields to match your target U-factor.
To confirm/view thermal performance post-simulation you can look in the Envelope Summary section of the eplustbl.htm file. Additionally, you can use/write an EnergyPlus Measure for OpenStudio (see the Measure Writing Guide) to add additional output file formats and change the unit conversion from SI to IP (see the OutputControl:Table:Style object in the Input Output Reference PDF - it's not in Big Ladder's online version).