Question-and-Answer Resource for the Building Energy Modeling Community
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You might start learning your way around the OpenStudio API by reading select portions of the Measure Writing Guide. Much of this is specific to using the OpenStudio API inside the structure of a "measure", but there is some content that will explain the API itself. From the link, pay particular attention to the section titled "What Methods Are Available".
The API is ground zero. You will probably need to devise your own scheme to expose this API through a web service that meets the needs of your application. With any luck there are people in this community who can share their experiences in this area.
