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As Denis said, generally.
For your specific application, which is modeling one room as part of a larger building, the easiest is to put one wall as Outdoors
and the 3 "inside" walls as Adiabatic
. This will negate the heat transfer from these wall. This assumption is fine only if you think you have similar temperatures on both sides of the inside walls (eg: it's another office/room with the same thermostat setpoint on the other side).
If you have different conditions, you can use a SurfaceProperty:OtherSideCoefficients for example to set a specific temperature / temperature equation on the other side, but this is slightly more complicated.