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The GetSpecificHeatGlycol algorithm in EnergyPlus is called to check the fluid properties for ANY plant loop where a liquid circulates -- even if that loop doesn't contain glycol. You can see this reflected in your warning line:

* Warning * GetSpecificHeatGlycol: Temperature is out of range (too high) for fluid [WATER]

You can see the EnergyPlus source code where this algorithm is defined here. In your case, a water plant loop is experiencing a temperature of 125 oC, which is above water's boiling temperature. This could be happening during no- or low-flow periods, and you can read more about this in other posts here and here and here.

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The GetSpecificHeatGlycol algorithm in EnergyPlus is called to check the fluid properties for ANY plant loop where a liquid circulates -- even if that loop doesn't contain glycol. You can see this reflected in your warning line:

* Warning * GetSpecificHeatGlycol: Temperature is out of range (too high) for fluid [WATER]

You can see the EnergyPlus source code where this algorithm is defined here. In your case, a water plant loop is experiencing a temperature of 125 oC, which is above water's boiling temperature. This could be happening during no- or low-flow periods, and you can read more about this in other posts here and here and here.