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For more background about how the BCVTB works, I suggest apart from the BCVTB manual, the excellent book about Ptolemy II. The BCVTB is a special configuration of Ptolemy II, hence you can check the book for the underlying technology. The book and various papers about Ptolemy II can be accessed at https://ptolemy.eecs.berkeley.edu/
For modeling of control, I suggest you also look into Modelica. See also http://www.iea-annex60.org/pubs.html for various related publications and a recent book about Modelica for building energy and control systems.