A partial selection of concepts to consider. Based on your description, I'm assuming that there is a modelled pair of adjacent interzone walls separating both zones. And that each interzone wall holds a conventional interzone window, i.e. no Construction:AirBoundary objects involved. Given that, I'm simply drawing your attention to the following specific points of discussion in the Engineering Reference:
 
 Solar Distribution, in particular the options FullInteriorAndExterior and FulInteriorAndlExteriorWithReflections. This is set in the IDF using the Building object. These options come with a price with regards to zone geometry (enclosed, convex), yet ensure that some of the transmitted beam solar radiation may make its way to the adjacent zone (through the interzone window). An excerpt:
  If you use FullInteriorAndExterior the
  program will calculate how much beam
  radiation falling on an interior
  window is absorbed by the window, how
  much is reflected back into the zone,
  and how much is transmitted into the
  adjacent zone.
 
 
 Details of the Interior Solar Distribution Calculation, quoting:
  EnergyPlus calculates the distribution
  of short-wave radiation in the
  interior of each thermal zone. This
  radiation consists of beam solar
  radiation, diffuse solar
  radiation, and short-wave radiation
  from electric lights. The program
  determines the amount of this
  radiation that is (1) absorbed on the
  inside face of opaque surfaces, (2)
  absorbed in the glass and shading
  device layers of the zone’s exterior
  and interior windows, (3)
  transmitted through the zone’s
  interior windows to adjacent zones, and (4) transmitted back out
  of the exterior windows.
 
 
 Interior Diffuse Radiation, again quoting (towards the end):
  [...] taking into account multiple
  reflection between zones. For example,
  for two zones means that some of the
  radiation transmitted from Zone1 to
  Zone2 is reflected back to Zone1, and
  some of this is in turn reflected back
  to Zone2, etc.
 
 
 Interior Solar Radiation Transmitted by Interior Windows, notably the different treatment of beam vs diffuse:
  The program does not track where this
  radiation falls in the adjacent
  zone: it is counted as diffuse
  radiation in that zone.
 
 Hope these excerpts help you.
 
 EDIT: In a nutshell, as long as you're selecting either FullInteriorAndExterior or FulInteriorAndlExteriorWithReflections as the Building's Solar Distribution option, and that zone geometry is enclosed & convex, you'll get just about what you're looking for.
 
   
Which application? EnergyPlus?
Hi Denis, sorry I should have mentioned earlier. Yes I am working on EnergyPlus.